Stress-induced roughness development during oxide scale growth on a metallic alloy for SOFC interconnects
نویسندگان
چکیده
Fe3Al intermetallics (Fe3Al, Fe3Al-Zr, Fe3Al-Zr,Mo and Fe3Al-Zr,Mo,Nb) were oxidized at 950 C in dry and humid (11 vol% water) synthetic air. Thermogravimetric measurements showed that the oxidation rates of the tested intermetallics were lower in humid air than in dry air (especially for Fe3Al-Zr,Mo and Fe3Al-Zr,Mo,Nb). The addition of small amounts of Zr, Mo or Nb improved the kinetics compared with that of the undoped Fe3Al. Fe3Al showed massive spallation, whereas Fe3Al-Zr, Fe3Al-Zr,Mo and Fe3Al-Zr,Mo,Nb produced a flat, adherent oxide layer. The rapid transformation of transient alumina into alpha alumina may explain the decrease in the oxidation rate in humid air.
منابع مشابه
Copper Manganese Spinel Coating on a Ferritic Stainless Steel for SOFC Application
Nowadays, Because of daily reduction of fossil fuels and environmental problems caused by using them, Fuel Cells attracted a major attention as clean and efficient way of generating electrical power. Solid Oxide Fuel Cells (SOFCs) have many advantages to other fuel cell types. High working temperature of SOFCs caused serious challenges including high oxidation rate of interconnects, Spallation ...
متن کاملElectrophoretic deposition of MnCr2O4 coating for solid oxide fuel cell metallic interconnects
In the present study, Mn - Cr spinel powder was synthesized through a solid state reaction. In the next step, the electrophoretic deposition (EPD) method was used to apply the MnCr2O4 spinel, as an oxidation-resistant layer, on SUS 430 stainless steel in a potential of 300 V/cm. The coated and uncoated samples were then pre-sintered in air at 900 °C for 3 h followed by cyclic oxidation at 800 °...
متن کاملDevelopment of a Chromium Vaporization Measurement System
One factor limiting solid oxide fuel cell (SOFC) performance is the degradation of chromium containing, ferritic stainless steel, interconnects during operation. When chromium-containing steels are used as interconnect materials a chromium oxide layer forms on the surface. Under SOFC operating conditions (Cathode gas 800oC and 2.5-3.1% H2O) chromium ions are vaporized by the cathode gas and red...
متن کاملSimulation of SOFC stack and repeat elements including interconnect degradation and anode reoxidation risk
Reliability of SOFC stacks is a complex and key issue. This paper presents a simulation study including some degradation processes, namely nterconnect degradation and the anode reoxidation potential. Quantification for these phenomena has been included in a repeat element model to imulate stack degradation and study the influence of design and operating parameters on the degradation. Interconne...
متن کاملSolid oxide fuel cell interconnect design optimization considering the thermal stresses
The mechanical failure of solid oxide fuel cell (SOFC) components may cause cracks with consequences such as gas leakage, structure instability and reduction of cell lifetime. A comprehensive 3D model of the thermal stresses of an anode-supported planar SOFC is presented in this work. The main objective of this paper is to get an interconnect optimized design by evaluating the thermal stresses ...
متن کامل